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Red Hat Customer
I searched and searched and searched, and the only place I could find the <domain name='...'/> setting that can be put into the XML for a libvert network is in a brief mention in a bugzilla ticket. This really needs to be documented better somewhere -- what the syntax is, what it does, etc. It also really should be exposed in virt-manager, but that's a different bug (which I will file separately).
Filed bug 1171192 about virt-manager.
The element is documented on the 'Network XML format' page: http://libvirt.org/formatnetwork.html#elementsConnect