The STARTTLS option of SMTP is ignored, when "Server requires authentication" is not checked. In this case kmail will send any mail in cleartext. References: https://bugs.kde.org/show_bug.cgi?id=423423
Created kmail tracking bugs for this issue: Affects: fedora-all [bug 1995181]
I'll do some more digging but according to the manifest kdepim has been removed from RHEL (since 2019-09-10).
kmail is susceptible to a confidentially leak if "Server requires authentication" not checked in UI. The issue in a nutshell is this could lead to information not being encrypted that otherwise would be. analysis is complete, trackers have been filed. Closing.