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I have two i586 machines running RH6.0 Machine A has a CD-ROM drive which it mounts (ro) on /mnt/cdrom, and NFS-exports it (ro) to Machine B. If I mount /mnt/cdrom on Machine A, then on machine B, unmount on machine B, and then attempt to umount it on machine A, I'm told that the filesystem is busy. Consequently I have to reboot the machine to eject the CD-ROM, which is a real pain.
Yes, you are not going to need to un-export the cdrom before you are going to be able to unmount the drive. NFS is "using" it and therefore you are getting the message that you are seeing.