In xsane-0.30-2.i386.rpm , the post-install script contains the line: ln -s ../../../bin/xsane /usr/lib/gimp/1.0/plug-ins/xsane which is an attempt to make xsane work as a gimp plugin. That's great, except there's one "../" missing, so this line makes a symlink to /usr/lib/bin/xsane instead of /usr/bin/xsane. The line should really be: ln -s ../../../../bin/xsane /usr/lib/gimp/1.0/plug-ins/xsane Then it will work :-)
Check out xsane-0.47-2 in rawhide whenever it gets updated. It's now fixed.